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Title 

An efficient indium-mediated 2-bromoallylation of aldehydes at low temperature in aqueous DMF

Authors 

Y M KimSangku LeeS H KimJ N Kim

Publisher 

Elsevier

Issue Date 

2011

Citation 

Tetrahedron Letters, vol. 52, no. 25, pp. 3240-3242

Keywords 

2-BromoallylationAlleneBarbier reactionIndium

Abstract 

An efficient synthesis of 2-bromohomoallylic alcohols was carried out via an indium-mediated Barbier-type 2-bromoallylation of aldehydes in moderate yields. The reaction was performed at low temperature (-20 °C) in aqueous DMF in order to minimize decomposition of 2-bromoallylindium reagent to allene.

ISSN 

0040-4039

Link 

http://dx.doi.org/10.1016/j.tetlet.2011.04.053

Appears in Collections

1. Journal Articles > Journal Articles

Registered Date

2017-04-19


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