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Title 

Direct one-pot introduction of 2-methylpyridines to Baylis-Hillman adducts via base-mediated 3-aza-Cope rearrangement

Authors 

H S LeeSangku LeeS H KimJ N Kim

Publisher 

Elsevier

Issue Date 

2011

Citation 

Tetrahedron Letters, vol. 52, no. 39, pp. 5039-5042

Keywords 

2-MethylpyridinesAza-Cope rearrangementBaylis-Hillman adducts

Abstract 

An efficient and regioselective introduction method of 2-methylpyridines to the secondary position of Baylis-Hillman adducts has been developed. A base treatment of 2-methylpyridinium salt of Baylis-Hillman bromide generated N-allylenamine intermediate which underwent a facile 3-aza-Cope rearrangement under mild conditions to produce the product.

ISSN 

0040-4039

Link 

http://dx.doi.org/10.1016/j.tetlet.2011.07.101

Appears in Collections

1. Journal Articles > Journal Articles

Registered Date

2017-04-19


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