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Title 

Expedient synthesis of 4-O-methylhonokiol via Suzuki-Miyaura cross-coupling

 

스즈끼 반응을 이용한 메틸호노키올의 효율적 전합성

Authors 

J H KwakYoung Ae ChoJ Y JangS Y SeoH LeeJ T HongS B HanK LeeYoung Shin KwakJ K Jung

Publisher 

Elsevier

Issue Date 

2011

Citation 

Tetrahedron, vol. 67, no. 48, pp. 9401-9404

Keywords 

4-O-MethylhonokiolNeolignanPotassium aryltrifluoroborateSuzuki-Miyaura cross-coupling

Abstract 

Concise and practical synthesis of 4-O-methylhonokiol was achieved in 34% overall yield. The key features of our synthesis include chemoselective ortho-mono bromination of phenol as well as biaryl formation via Suzuki-Miyaura cross-coupling, in which bromophenol was reacted with potassium aryltrifluoroborate using Pd(OAc)2 and RuPhos under microwave conditions.

ISSN 

0040-4020

Link 

http://dx.doi.org/10.1016/j.tet.2011.09.115

Appears in Collections

1. Journal Articles > Journal Articles

Registered Date

2017-04-19


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