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Title 

Enzymatic preparation of optically active 2-acetoxymethylglycidol, a new chiral building block in natural product synthesis

Authors 

Young Bae SeuYung Hee Kho

Publisher 

Elsevier

Issue Date 

1992

Citation 

Tetrahedron Letters, vol. 33, no. 46, pp. 7015-7016

Keywords 

2 acetoxymethylglycidolalkanolglycerol derivativetriacylglycerol lipaseunclassified drugenantiomerenzyme activitypriority journalsynthesis

Abstract 

Asymmetric hydrolysis of geminally disubstituted achiral diacetate 2 with lipase PPL yielded optically active (R)-(-)-2-acetoxymethylglycidol 3 and its reduction gave compound 6, useful as the tert-alcohol chiral building block.

ISSN 

0040-4039

Appears in Collections

1. Journal Articles > Journal Articles

Registered Date

2017-04-19


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