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Title 

Stereochemistry of phellinsin A: a concise synthesis of α-arylidene-γ-lactones

Authors 

EungSoo KimHyeong Kyu LeeEui Il HwangSung Uk KimWoo Song LeeSangku LeeS H Jung

Publisher 

Taylor & Francis

Issue Date 

2005

Citation 

Synthetic Communications, vol. 35, no. 9, pp. 1231-1238

Keywords 

α-Arylidene-γ-lactonecinnamic aciddilactonehydrolysisalpha arylidene gamma lactonechitin synthasecinnamic acid derivativelactone derivativelead oxide

Abstract 

Phellinsin A (1a) was prepared in a concise way, thereby elucidating the relative stereochemistry of the aryl and carboxylic acid groups in 1a. The synthesis employed selective monohydrolysis of the dilactones derived from oxidative dimerization of cinnamic acid derivatives. This approach provided a practical synthetic route to α-arylidene-γ-lactones.

ISSN 

0039-7911

Link 

http://dx.doi.org/10.1081/SCC-200054845

Appears in Collections

1. Journal Articles > Journal Articles

Registered Date

2017-04-19


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